I have not had the time to read everything in this post, but as DDDamian surely can confirm i've had almost every sync issue there is to have
Status as of today however is that the 24fps sync bug is pretty much sorted out for my part.
I could never get my Nvidia GT520 card to sync up properly so I switched to a 6450 card and it improved. I did not get perfect sync every time, but it improved alot.
After a while AMD gave out the Catalyst 12.6 Beta driver which resolved the HDMI handshake problem amongst other things... the documentation on the driver did not state anything about audiosync issues, but with this driver, the 6450 and Frodo A2 I got almost perfect sync.
Today I'm running Catalyst 12.6 Beta, 6450 and Frodo A3, and as far as I can see I have as close to perfect sync as it's possible to get. No dropped frames unless I pause, FastForward or something like that.
I don't know if there has been much work on the sync issue between Frodo A2 and A3, but I got an improvement between the two...
The only thing I'm having issues with now is a bit jerky playback on 29.970 fps material... this was no problem on Eden, but since I have very little 29.970 material I really don't care;p
System: XBMC Gotham 13.1, HTPC: AMD 6450 1GB, Intel i5 3470S, 8GB DDR3, ASUS P8H61-M PRO, OCZ SSD Agility 3, NYXboard Hybrid Remote
Surround: NAD M15HD2, NAD M25, B&W 803 Diamond, B&W DB1, B&W HTM4, Pioneer KRP-600A / Panasonic 65VT50