Building a dual boot, can I share the shares?

Hey all,

I am a long time PC guy, but am upgrading my rig substantially and moving in with a girl simultaniously. She prefers OSX to Windows 7, so I'd like to dual boot my pc between the two with a Hackintosh build.

Currently this pc has 10 HDDs totalling roughly 10 TBs of space, all shared via SMB. What I want to be sure of is that I can boot into either OS and have the shares on my xbmc build elsewhere on the network work the same. I use no passwords, just shares. Can I configure OSX to do that, or are the shares going to not be in the SMB://PCNAME/TV Directory?

Thanks